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Question

Chemistry Question on Thermodynamics

For the reaction, 2NO(g)+O2(g)2NO2(g),2 NO (g)+ O _{2}(g) \rightleftharpoons 2 NO _{2}(g), increase in pressure favours the formation of NO2NO _{2}. The reaction is exothermic.

A

If both Assertion and Reason are true and the Reason is the correct explanation of the Assertion

B

If both Assertion and Reason are true but the Reason is not the correct explanation of the Assertion

C

If Assertion is true but Reason is false

D

If both Assertion and Reason are false

Answer

If both Assertion and Reason are true but the Reason is not the correct explanation of the Assertion

Explanation

Solution

2NO+O22NO22 NO + O _{2} \rightleftharpoons 2 NO _{2} In this reaction, Number of moles of gaseous reactants, nr=3n_{r}=3 Number of moles of gaseous products, np=2n_{p}= 2 Since, npn_{p} is less than nrn_{r}, according to Le-Chatelier principle, increase in pressure shifts the equilibrium in forward direction, ie, more NO2NO _{2} is formed. The reaction given above is exothermic.