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Question: For the decomposition of HI the following logarithmic plot is shown : [R = 1.98 cal/mol-K] The acti...

For the decomposition of HI the following logarithmic plot is shown : [R = 1.98 cal/mol-K]

The activation energy of the reaction is about

A

45600 cal

B

13500 cal

C

24600 cal

D

32300 cal

Answer

45600 cal

Explanation

Solution

=Ea2.303R×103×103Tconstant= - \frac{E_{a}}{2.303R} \times 10^{- 3} \times \frac{10^{3}}{T}cons\tan t thus, slope of

graph will beEa×1032.303R=40.4- \frac{E_{a} \times 10^{- 3}}{2.303R} = - \frac{4}{0.4}

Ea=2.303×1.98×104=45600cal\Rightarrow E_{a} = 2.303 \times 1.98 \times 10^{4} = 45600cal