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Question: For NaCl ,lattice energy = – 186 kcal/mol, the solvation energy of Na<sup>+</sup> and Cl<sup>–</sup>...

For NaCl ,lattice energy = – 186 kcal/mol, the solvation energy of Na+ and Cl are –97 and – 85 kcal/mole respectively. Therefore for NaCl (s)

A

Enthalpy of solution is exothermic and magnitude equal 4 kcal/mol.

B

Enthalpy of solution is exothermic and magnitude equal to 368 kcal/mol

C

Enthalpy of solution is endothermic and magnitude equal to 4 kcal/mol

D

Enthalpy of solution is endothermic and magnitude equal to 368 kcal/mol

Answer

Enthalpy of solution is endothermic and magnitude equal to 4 kcal/mol

Explanation

Solution

∆H solv = –97–85 = –182 kcal/mol

–LE = + 186 kcal/mol

∆H (solution) = + 186 – 182 = 4 kcal/mol & endothermic