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Question

Chemistry Question on Thermodynamics

For isothermal expansion of an ideal gas, the correct combination of the thermodynamic parameters will be

A

$?U = 0, Q=0, w ?

B

$?U ?

C

$?U = 0, Q?

D

$?U = 0, Q?

Answer

$?U = 0, Q?

Explanation

Solution

For isothermal expansion of an ideal gas ΔT=0\Delta T=0 From ΔU=nCvΔT\Delta U=n C _{v} \Delta T, ΔU=0\Delta U=0 and, from ΔH=nCρΔt=0\Delta H=n C _{\rho} \Delta t=0 From first law of thermodynamics, as ΔU=Q+W\Delta U=Q+W ΔU=0Q0\Delta U=0 \Rightarrow Q \neq 0 and W0W \neq 0 \therefore Parameters are ΔU=0,Q0;W0\Delta U=0, Q \neq 0 ; W \neq 0 and ΔH=0\Delta H=0