Question
Chemistry Question on Thermodynamics
For isothermal expansion of an ideal gas, the correct combination of the thermodynamic parameters will be
A
$?U = 0, Q=0, w ?
B
$?U ?
C
$?U = 0, Q?
D
$?U = 0, Q?
Answer
$?U = 0, Q?
Explanation
Solution
For isothermal expansion of an ideal gas ΔT=0 From ΔU=nCvΔT, ΔU=0 and, from ΔH=nCρΔt=0 From first law of thermodynamics, as ΔU=Q+W ΔU=0⇒Q=0 and W=0 ∴ Parameters are ΔU=0,Q=0;W=0 and ΔH=0