Question
Chemistry Question on Solutions
For He+, a transition takes place from the orbit of radius 105.8 pm to the orbit of radius 26.45 pm. The wavelength (in nm) of the emitted photon during the transition is ___.
[Use: Bohr radius, a = 52.9 pm, Rydberg constant, 𝑅H = 2.2 × 10−18 J, Planck’s constant, h = 6.6 × 10−34 J s, Speed of light, c = 3 × 108 m s−1]
Answer
r=52.9×zn2pm
∴105.8=252.9×n2∴n2=2
and 26.45=52.9×2n2∴n1=1
∵ ΔE=RHhC×z2[n121−n221]
λhc=RHhC×z2[n121−n221]
λ6.6×10−34×3×108=2.2×10−18×4×43
∴ λ=300A˚
∴λ=30nm
The wavelength of the emitted photon is 30 nm.