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Question

Chemistry Question on States of matter

For gaseous state, if most probable speed is denoted by cc *, average speed by C\overline{C} and root square speed by cc, then for a large number of molecules, the ratios of these speeds are

A

c:c:c=1.225:1.128:1c^* : \overline{c} : c = 1.225 : 1.128 : 1

B

c:c:c=1.128:1.225:1c^* : \overline{c} : c = 1.128 : 1.225 : 1

C

c:c:c=1:1.128:1.225c^* : \overline{c} : c = 1 : 1.128 : 1.225

D

c:c:c=1:1.225:1.128c^* : \overline{c} : c = 1 : 1.225 : 1.128

Answer

c:c:c=1:1.128:1.225c^* : \overline{c} : c = 1 : 1.128 : 1.225

Explanation

Solution

C * = Most probable speed 2RTM\sqrt{\frac{2RT}{M}}
C\overline{C}= Average speed = 8RTπM\sqrt{\frac{8RT}{\pi M}}
C = Root square speed corrected as root means square speed, i.e
rms=3RTMrms=\sqrt{\frac{3RT}{M}} and as we know C<C<C\, ^{*}_{C} < \overline{C} < C
C:C:C=1:4p:32=1:1.128:1.225\, ^{*}_{C} : \overline{C} : C=1 : \sqrt{\frac{4}{p}} : \sqrt{\frac{3}{2}}= 1 : 1.128 : 1.225
NOTE
As no option correspond to root square speed, it is understood as misprint. It should be root mean square speed.