Question
Chemistry Question on The solid state
For FCC if AB is just like the rock salt like structure then, A+ and B- are located at -
A
A+ - Tetrahedral voids ; B− - Corner
B
A+ - Corner and faces ; B− - Octahedral voids
C
A+ - Octahedral voids ; B− - Corner and faces
D
A+ - Corner and faces ; B− - Octahedral and tetrahedral voids
Answer
A+ - Octahedral voids ; B− - Corner and faces
Explanation
Solution
AB is just like NaCl. Thus twelve A+ are at edges and 1 within body of fcc i.e. in octahedral voids and six B− at faces and 8 at corner.