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Question

Chemistry Question on The solid state

For FCC if AB is just like the rock salt like structure then, A+ and B- are located at -

A

A+A^+ - Tetrahedral voids ; BB^- - Corner

B

A+A^+ - Corner and faces ; BB^- - Octahedral voids

C

A+A^+ - Octahedral voids ; BB^- - Corner and faces

D

A+A^+ - Corner and faces ; BB^- - Octahedral and tetrahedral voids

Answer

A+A^+ - Octahedral voids ; BB^- - Corner and faces

Explanation

Solution

AB is just like NaCl. Thus twelve A+A^+ are at edges and 1 within body of fcc i.e. in octahedral voids and six BB^- at faces and 8 at corner.