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Question

Chemistry Question on Chemical bonding and molecular structure

For diatomic molecules, the correct statement(s) about the molecular orbitals formed by the overlap to two 2pz2 p_z orbitals is(are)

A

σ\sigma orbital has a total of two nodal planes.

B

σ\sigma^* orbital has one node in the xzx z-plane containing the molecular axis.

C

π\pi orbital has one node in the plane which is perpendicular to the molecular axis and goes through the center of the molecule.

D

π\pi^* orbital has one node in the xyx y-plane containing the molecular axis.

Answer

σ\sigma orbital has a total of two nodal planes.

Explanation

Solution

A) π orbital has one node
B) π orbital has one node
C) π orbital has one node
D)π orbital has one node

So the correct answer is Option(A) and (D) :σ orbital has a total of two nodal planes and ππ^*orbital has one node in the xyxy-plane containing the molecular axis.