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Question

Chemistry Question on Thermodynamics

For diatomic ideal gas in a closed system, which of the following plots does not correctly describe the relation between various thermodynamic quantities ?

A

B

C

D

Answer

Explanation

Solution

At higher temperature, rotational degree of freedom becomes active. CP=72RC_{P} = \frac{7}{2} R (Independent of P) CV=52RC_{V} = \frac{5}{2} R (Independent of V) Variation of UU vs TT is similar as CVC_V vs TT.