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Question: For coagulating \(A s _ { 2 } S _ { 3 }\) colloidal sol, which of the following will have the lowest...

For coagulating As2S3A s _ { 2 } S _ { 3 } colloidal sol, which of the following will have the lowest coagulation value.

A

NaCl

B

KCl

C

BaCl2\mathrm { BaCl } _ { 2 }

D

AlCl3\mathrm { AlCl } _ { 3 }

Answer

AlCl3\mathrm { AlCl } _ { 3 }

Explanation

Solution

The amount of electrolyte required to coagulate a fixed amount of a solution depends upon the valency of the flocculation ion. The flocculating power of the various ions follows the following order, larger the valency lesser will be coagulating value. Al3+>Mg2+>Na+\mathrm { Al } ^ { 3 + } > \mathrm { Mg } ^ { 2 + } > \mathrm { Na } ^ { + } , hence lowest coagulation value is of AlCl3\mathrm { AlCl } _ { 3 }..