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Question

Chemistry Question on Thermodynamics

For a sample of perfect gas when its pressure is changed isothermally from pip_i to pfp_f, the entropy change is given by

A

ΔS=nRln(Pfpi)\Delta S = nR \, ln \bigg( \frac{P_f}{p_i}\bigg)

B

ΔS=nRln(pipf)\Delta S = nR \, ln \bigg( \frac{p_i}{p_f}\bigg)

C

ΔS=nRTln(pfpi)\Delta S = nRT\, ln \bigg( \frac{p_f}{p_i}\bigg)

D

ΔS=RTln(pipf)\Delta S = RT \, ln \bigg( \frac{p_i}{p_f}\bigg)

Answer

ΔS=nRln(pipf)\Delta S = nR \, ln \bigg( \frac{p_i}{p_f}\bigg)

Explanation

Solution

ΔS=nRlnP1Pf\Delta S = nR \, ln \frac{P_1}{P_f}