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Question: For a reaction, P + Q \(\rightarrow\) R + S. The value of \(\Delta H^{o}\)is \(- 30kJmol^{- 1}and\De...

For a reaction, P + Q \rightarrow R + S. The value of ΔHo\Delta H^{o}is 30kJmol1andΔSis100JK1mol1- 30kJmol^{- 1}and\Delta Sis - 100JK^{- 1}mol^{- 1} At what temperature the reaction will be at equilibrium?

A

27oC27^{o}C

B

52oC52^{o}C

C

30oC30^{o}C

D

45oC45^{o}C

Answer

27oC27^{o}C

Explanation

Solution

: ΔG=ΔHTΔS,\Delta G = \Delta H - T\Delta S,

At equilibrium, ΔG=0,ΔH=TΔS\Delta G = 0,\Delta H = T\Delta S

30000 = T ×100

T = 300 K or 27oC27^{o}C