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Question

Chemistry Question on Equilibrium Constant

For a reaction H2+I22HIH _{2}+ I _{2} \rightleftharpoons 2 HI at 721K721\, K, the value of equilibrium constant is 5050. If 0.50.5 moles each of H2H_{2} and I2I_{2} is added to the system, the value of equilibrium constant will be:

A

40

B

60

C

50

D

30

Answer

50

Explanation

Solution

The equilibrium reaction is H2(g)+I2(g)2HI(g)H _{2}( g )+ I _{2}( g ) \rightarrow 2 HI ( g ). The relationship between KpKp and KcKc is Kp=Kc(RT)ΔnKp = Kc ( RT )^{\Delta n }. For the equilibrium reaction, Δn=2(1+1)=0\Delta n =2-(1+1)=0. Hence, Kp=Kc=50Kp = Kc =50.