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Question

Chemistry Question on Equilibrium

For a reaction, C(s)+CO2(g)2CO(g)C_{(s)}+C O_{2}(g) \rightarrow 2 C O_{(g)}; the partial pressure of CO2C O_{2} and COC O are 44 and 88 atm, respectively. KpK_{p} for the reaction is

A

0.5

B

2

C

16

D

4

Answer

16

Explanation

Solution

C(S)+CO2(g)2CO(g)C(S)+C O_{2}(g) \rightarrow 2 C O(g) Applying the law of mass action
Kp=(pCO)2(pC)(pCO2)K_{p}=\frac{\left(p_{C O}\right)^{2}}{\left(p_{C}\right)\left(p_{C O_{2}}\right)}
Given, pCO=8p_{C O}=8 atm
pCO2=4p_{C O_{2}}=4 atm and for solid C(S)pC=1C(S) p_{C}=1
Kp=(8)21×4\therefore K_{p}=\frac{(8)^{2}}{1 \times 4}
Kp=644=16\Rightarrow K_{p}=\frac{64}{4}=16