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Question

Chemistry Question on Chemical Kinetics

For a reaction AK1BK2CA \xrightarrow{K_1} B \xrightarrow{K_2} C If the rate of formation of B is set to be zero then the concentration of B is given by:

A

K1K2[A]K_1K_2[A]

B

(K1K2)[A](K_1 - K_2)[A]

C

(K1+K2)[A](K_1 + K_2)[A]

D

(K1/K2)[A](K_1/K_2)[A]

Answer

(K1/K2)[A](K_1/K_2)[A]

Explanation

Solution

The rate of formation of B is:
d[B]dt=k1[A]k2[B].\frac{d[\text{B}]}{dt} = k_1[\text{A}] - k_2[\text{B}].
For the rate of formation of B to be zero:
d[B]dt=0.\frac{d[\text{B}]}{dt} = 0.
Substitute:
k1[A]k2[B]=0.k_1[\text{A}] - k_2[\text{B}] = 0.
Rearrange to find [B]:
k1[A]=k2[B]    [B]=k1k2[A].k_1[\text{A}] = k_2[\text{B}] \implies [\text{B}] = \frac{k_1}{k_2}[\text{A}].
Thus, the concentration of B is:
[B]=(k1k2)[A].[\text{B}] = \left(\frac{k_1}{k_2}\right)[\text{A}].