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Question: For a particular reaction variation of rate constant with temperature is given by ln k<sub>t</sub> ...

For a particular reaction variation of rate constant with temperature is given by

ln kt = ln k0 + (ln310)t\left( \frac{\mathcal{l}n3}{10} \right)t (t ≥ 0°C)

Temp. Coefficient of reaction is –

A

4

B

3

C

10

D

2

Answer

3

Explanation

Solution

We know kt2k_{t_{2}}= kt1k_{t_{1}} (m) t2t110\frac{t_{2}–t_{1}}{10}

OR ln kt2k_{t_{2}} = ln kt1k_{t_{1}}+ t2t110\frac{t_{2}–t_{1}}{10} ln m

putting t1 = 0

ln kt2k_{t_{2}} = ln k + t210\frac{t_{2}}{10} ln m

Comparing with ln kt = ln k0 + ln33t\frac{\mathcal{l}n3}{3}t

M = 3