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Question

Chemistry Question on Order of Reaction

For a first order reaction, the time required for completion of 90% reaction is ‘x’ times the half life of the reaction. The value of ‘x’ is (Given: In 10 = 2.303 and log 2 = 0.3010)

A

1.12

B

2.43

C

3.32

D

33.31

Answer

3.32

Explanation

Solution

A → Products

For a first order reaction,

t1/2=ln2k=0.693kt_{1/2} = \frac{ln2}{k} = \frac{0.693 }{ k}

Time for 90%90\% conversion,

t90%=1k  In  10010=ln10k=2.303kt_{ 90\%} = \frac{1}{k} \;In \;\frac{100}{10 }= \frac{ln10}{k} = \frac{2.303}{k}

t90%=2.3030.693  t1/2=3.32  t1/2t_{90\%} = \frac{2.303}{0.693} \;t_{1/2} = 3.32 \;t_{1/2}