Question
Question: For 10<sup>–2</sup>(M) H<sub>3</sub>PO<sub>3</sub> solution which of the following relations is corr...
For 10–2(M) H3PO3 solution which of the following relations is correct ?
A
[H3PO3] + [H2PO3–] + [HPO32–] + [PO32–] = 10–2
B
[H3PO3] + [H2PO3–] + [HPO32–] = 10–2
C
[H2PO3–] + [HPO32–] + [PO33–] = 10–2
D
[H3PO3] + [H2PO3–] + 2[HPO32–] = 10–2
Answer
H<sub>3</sub>PO<sub>3</sub> + H2PO3– + HPO32– = 10–2
Explanation
Solution
H3PO3 ⇄ H2PO3– + H+
H2PO3– ⇄ HPO32–+ H+
H3PO3 is a dibasic acid