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Question: For 10<sup>–2</sup>(M) H<sub>3</sub>PO<sub>3</sub> solution which of the following relations is corr...

For 10–2(M) H3PO3 solution which of the following relations is correct ?

A

[H3PO3] + [H2PO3H_{2}PO_{3}^{–}] + [HPO32HPO_{3}^{2–}] + [PO32PO_{3}^{2–}] = 10–2

B

[H3PO3] + [H2PO3H_{2}PO_{3}^{–}] + [HPO32HPO_{3}^{2–}] = 10–2

C

[H2PO3H_{2}PO_{3}^{–}] + [HPO32HPO_{3}^{2–}] + [PO33PO_{3}^{3–}] = 10–2

D

[H3PO3] + [H2PO3H_{2}PO_{3}^{–}] + 2[HPO32PO_{3}^{2–}] = 10–2

Answer

H<sub>3</sub>PO<sub>3</sub>H<sub>3</sub>PO<sub>3</sub> + H2PO3H_{2}PO_{3}^{–} + HPO32HPO_{3}^{2–} = 10–2

Explanation

Solution

H3PO3 \rightleftarrows H2PO3H_{2}PO_{3}^{–} + H+

H2PO3H_{2}PO_{3}^{–} \rightleftarrows HPO32HPO_{3}^{2–}+ H+

H3PO3 is a dibasic acid