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Question

Chemistry Question on Haloalkanes and Haloarenes

Following is the substitution reaction in which CN-CN replaces Cl-Cl
RCI+KCNΔRCN+KCIR - CI + KCN \overset{\Delta}{\rightarrow} R - CN + KCI
To obtain propane nitrile, RClR-Cl should be:

A

chloroethane

B

11-chloropropane

C

chloromethane

D

22-chloropropane

Answer

chloroethane

Explanation

Solution

C2H5Cl+KCN(alc)ΔC2H5CN+KClC _{2} H _{5}- Cl + \underset{(alc)}{KCN} \stackrel{\Delta}{\longrightarrow} C _{2} H _{5}- CN + KCl
Hence, to obtain propanenitrile, RClR- Cl should be chloroethane.