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Question

Chemistry Question on Molecular Orbital Theory

Fluorine molecule has bond order one. The number of electrons in the ant bonding molecular orbitals is two less than that in bonding molecular orbitals.

A

If both Assertion and Reason are true and the Reason is the correct explanation of the Assertion

B

If both Assertion and Reason are true but the reason is not the correct explanation of the Assertion

C

If Assertion is true but Reason is false

D

If both Assertion and Reason are false

Answer

If both Assertion and Reason are true and the Reason is the correct explanation of the Assertion

Explanation

Solution

MO electronic configuration of F2F _{2} molecule is F2=σ1s2,σ1s2,σ2s2,σ2s2,σ2px2,F _{2}=\sigma 1 s^{2}, \sigma^{*} 1 s^{2}, \sigma 2 s^{2}, \sigma^* 2 s^{2}, \sigma 2 p_{x}^{2}, π2py2π2pz2,π2py2π2pz2\pi 2 p_{y}^{2} \approx \pi 2 p_{z}^{2}, \pi^{*} 2 p_{y}^{2} \approx \pi^* 2 p_{z}^{2} Bond order =NbNa2=\frac{N_{b}-N_{a}}{2} where, Nb=N_{b}= Number of electrons in bonding molecular orbitals Na=N_{a}= Number of electrons in antibonding molecular orbitals =862=1=\frac{8-6}{2}=1