Question
Question: Find the temperature at which volume and pressure of \(28g\) nitrogen gas becomes \(10d{m^3}\) and \...
Find the temperature at which volume and pressure of 28g nitrogen gas becomes 10dm3 and 2.46atm respectively.
A.1200K
B.600K
C.300K
D.900K
Solution
The relation between the temperature, pressure and volume of a gas is given by the formula,
PV=nRT
This equation is the ideal gas equation.
The units of pressure, volume and temperature considered in the above equation are atm, L and K respectively. So, the corresponding unit of R is LatmK−1mol−1.
Complete step by step answer:
Nitrogen gas exists as N2. So, the molar mass of nitrogen gas is
=2×14g
⇒28g
In the question, 28g nitrogen gas is present, therefore the number of moles of gas (n) present can be calculated by dividing the given mass of the gas by the molar mass of the gas.
So, n=2828
⇒n=1 mole
Volume of the gas is given to be 10dm3. We will convert dm3 into litre.
As, 1dm3=1L
So, 10dm3=10L
Pressure of the gas is 2.46atm and R is the universal gas constant whose value is 0.0821LatmK−1mol−1.
Putting these values in the ideal gas equation,
PV=nRT
⇒2.46×10=1×0.0821×T
⇒T=0.08212.46×10K
⇒T=300K
Thus, the answer is option C.
Note:
While considering the molar mass of the gas we should keep in mind the atomic state in which the gas exists, because gases like nitrogen, oxygen, etc. exist as diatomic gases (N2,O2); therefore, their diatomic masses should be considered while solving the question.
Also, the value of R is taken to be 0.0821LatmK−1mol−1 when the units of P and V are atm and L respectively. Whereas the value of R as 8.314JK−1mol−1 is taken when the units of P and V are Pa and m3 respectively.