Question
Question: Find the number of unsaturated products formed in given reaction ...
Find the number of unsaturated products formed in given reaction

2
Solution
Solution
-
The substrate is a cyclohexane derivative having a –Cl and a –CH₃ on one carbon (say C₂) with adjacent carbons (C₁ and C₃) being substituted by –CH₃ groups.
-
Under heat with alcoholic KOH, an E2 elimination occurs. The –Cl leaves from C₂ and a β–hydrogen is removed from either of the two adjacent carbons (C₁ or C₃).
-
This yields two different regioisomeric cyclohexene derivatives (one with the double bond between C₁–C₂ and the other between C₂–C₃).
-
In each cyclohexene product the double bond is part of the ring and fixed so that no additional E/Z isomerism is possible.
Thus, the reaction produces 2 unsaturated products.
Explanation (minimal):
-
Substrate has Cl at C₂ and β–hydrogens at C₁ and C₃.
-
E2 elimination with alc. KOH removes Cl from C₂ and a hydrogen from either C₁ or C₃.
-
This forms two distinct cyclohexenes (regioisomers); each double bond in the ring is fixed.