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Question: Find the number of faradays of electricity required to produce 45 g of Al from molten $Al_2O_3$. (A...

Find the number of faradays of electricity required to produce 45 g of Al from molten Al2O3Al_2O_3.

(At. mass of Al = 27)

A

1 F

B

3 F

C

5 F

D

7 F

Answer

5 F

Explanation

Solution

To determine the number of Faradays required to produce 45 g of Al from molten Al2O3Al_2O_3, we can follow these steps:

  1. Calculate moles of Al:

    The number of moles of Al can be found using the formula:

    Moles of Al=Mass of AlMolar mass of Al\text{Moles of Al} = \frac{\text{Mass of Al}}{\text{Molar mass of Al}}

    Given that the mass of Al is 45 g and the molar mass of Al is 27 g/mol:

    Moles of Al=45 g27 g/mol=53 moles\text{Moles of Al} = \frac{45~\text{g}}{27~\text{g/mol}} = \frac{5}{3} \text{ moles}
  2. Determine electrons required per mole of Al:

    The reduction half-reaction for aluminum is:

    Al3++3eAlAl^{3+} + 3e^- \rightarrow Al

    This indicates that 3 moles of electrons are required to produce 1 mole of Al.

  3. Calculate total moles of electrons:

    To find the total moles of electrons needed to produce 53\frac{5}{3} moles of Al:

    Total moles of electrons=53 moles Al×3moles emole Al=5 moles electrons\text{Total moles of electrons} = \frac{5}{3} \text{ moles Al} \times 3 \frac{\text{moles } e^-}{\text{mole Al}} = 5 \text{ moles electrons}
  4. Apply Faraday's Law:

    1 Faraday is equivalent to 1 mole of electrons. Therefore, 5 moles of electrons correspond to 5 Faradays.

Thus, the number of Faradays of electricity required to produce 45 g of Al from molten Al2O3Al_2O_3 is 5 F.