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Question

Chemistry Question on Nomenclature of Coordination Compounds

Facial and meridional isomerism will be exhibited by

A

[Co(NH3)3Cl3][Co(NH_3)_3Cl_3]

B

[Co(NH3)4Cl2]Cl[Co(NH_3)_4Cl_2]Cl

C

[Co(en)3]Cl3[Co(en)_3 ]Cl_3

D

[Co(NH3)5Cl)Cl2[Co(NH_3)_5Cl)Cl_2

Answer

[Co(NH3)3Cl3][Co(NH_3)_3Cl_3]

Explanation

Solution

Facial (fac) and meridional (mer) isomerism, a type of geometrical isomerism, is shown by octahedral complexes having Ma3b3Ma_3b_3 general formula. Where, Mis cenral metal and a and b are monodentate ligand. Hence, [Co(NH3)3Cl3][Co(NH_3 )_3 Cl_3] exhibits fac-mer isomerism as