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Question

Chemistry Question on The solid state

Experimentally it was found that a metal oxide has formula M0.98O.M_{0.98}O. Metal MM, present as M2+M^{2+} and M3+M^{3+} in its oxide.Fraction of the metal which exists as M3+M^{3+} would be

A

7.01%7.01 \%

B

4.08%4.08 \%

C

6.05%6.05 \%

D

5.08%5.08 \%

Answer

4.08%4.08 \%

Explanation

Solution

Let the fraction of metal which exists as M3+M^{3+} be xx.

Then the fraction of metal as M2+=(0.98x)M^{2+} = (0.98 - x)
3x+2(0.98x)=2\therefore 3x + 2(0.98 -x ) = 2
x+1.96=2x + 1.96 =2
x=0.04x = 0.04
%\therefore \% of M3+=0.040.98×100M^{3+}=\frac{0.04}{0.98}\times 100
=4.08%=4.08\%