Question
Question: Ethyl alcohol is industrially prepared from ethylene by \(A)\) Permanganate oxidation \(B)\) Cat...
Ethyl alcohol is industrially prepared from ethylene by
A) Permanganate oxidation
B) Catalytic reduction
C) Absorbing in H2SO4 followed by hydrolysis
D) Fermentation
Solution
The hydrocarbon ethylene (IUPAC name: ethene) has the formula C2H4 or H2C=CH2 . When pure, it's a colourless, flammable gas with a faint "sweet and musky" odour. It is the most basic alkene (a hydrocarbon with carbon-carbon double bonds).
Complete step by step answer:
Ethylene is a hormone present in plants that is used to force the ripening of fruits in agriculture. Ethanol is also known as ethyl alcohol, is the ethylene hydrate.
Ethylene absorbs H2SO4 to form ethyl sulphate (CH3−CH1−HSO4)
CH2=CH2H2SO4CH3−CH1−HSO4
The organic chemical compound ethyl sulphate (IUPAC name: ethyl hydrogen sulfate), also known as sulfonic acid, is a chemical that is used as a catalyst in the production of ethanol from ethylene. It's the sulfuric acid ethyl ester.
A chemical reaction where one or more chemical bonds are broken by a molecule of water is known as hydrolysis.
During hydrolysis, both ethyl sulphate and the water molecule will split into two. One fragment of the target molecule wins a hydrogen ion in such reactions. So, after hydrolysis, we get ethyl alcohol and H2SO4
CH3−CH1−HSO4HydrolysisCH3−CH2−OH+H2SO4
We can clearly notice that due to hydrolysis, ethyl sulphate converts into ethyl alcohol.
Therefore, option C) Absorbing in H2SO4 followed by hydrolysis is the correct answer.
Note: Ethylene is extensively in use in the chemical industry, and it produces more than any other organic compound (more than 150 million tonnes in 2016 ). Polyethylene, a commonly used plastic made up of polymer chains of ethylene units of different lengths, accounts for a significant portion of this output.