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Question

Chemistry Question on Amines

Ethanamine is treated with nitrous acid at ordinary temperature, the products will be

A

ethanol only

B

ethanol, acetic acid, N2andH20N_2\, and\, H_20

C

acetic acid, ethane and H20H_20

D

ethanol, ethene, ethyl chloride and N2N_2

Answer

ethanol, ethene, ethyl chloride and N2N_2

Explanation

Solution

{\underset{\mathrm{Ethylamine}}{ {C_2H_5 -NH_2 }}>[HONO/HCl][273278][H3CCH2N+NCl]>[Decomposes] ->[HONO/HCl][273 - 278] [H_3C -CH_2 - N^+ \equiv NCl^-] ->[Decomposes]\underset{\mathrm{Ethanol}}{ {[H_3C-CH_2 -OH ] }}+ H_2 C - CH_2 + CH_3 -CH_2 -Cl + N_2 }