Question
Chemistry Question on Amines
Ethanamine is treated with nitrous acid at ordinary temperature, the products will be
A
ethanol only
B
ethanol, acetic acid, N2andH20
C
acetic acid, ethane and H20
D
ethanol, ethene, ethyl chloride and N2
Answer
ethanol, ethene, ethyl chloride and N2
Explanation
Solution
{\underset{\mathrm{Ethylamine}}{ {C_2H_5 -NH_2 }}−>[HONO/HCl][273−278][H3C−CH2−N+≡NCl−]−>[Decomposes]\underset{\mathrm{Ethanol}}{ {[H_3C-CH_2 -OH ] }}+ H_2 C - CH_2 + CH_3 -CH_2 -Cl + N_2 }