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Question

Chemistry Question on d -and f -Block Elements

Equivalent mass of potassium permanganate in acid medium is

A

1/2 molecular mass

B

1/3 molecular mass

C

1/5 molecular mass

D

1/6 molecular mass.

Answer

1/5 molecular mass

Explanation

Solution

In acidic medium,
M+7nO4+8H++5e>Mn2++4H2O{M^{+7} nO^-_4 + 8H^+ + 5e^- -> Mn^{2+} + 4H_2O}
Total number of electrons gained = 5
Total change in the oxidation number of Mn = 7 - 2 = 5
EmassofKMnO4=Mol.massofKMnO45{E mass\, of \,KMnO_4 = \frac{ Mol.mass \, of\, KMnO_4}{5} }