Question
Chemistry Question on d -and f -Block Elements
Equivalent mass of K2Cr2O7 in acidic solution is equal to
A
molecular mass/2
B
molecular mass/4
C
molecular mass
D
molecular mass/6
Answer
molecular mass/6
Explanation
Solution
{\overset{\text{+6}}{ {C}}r_2 O^{2-}_7 + 14 H^+ + 6e^- -> 2Cr^{3+} + 7H_2O }
Total number of electrons gained = 6
Total change in oxidation number of Cr
???? =2(+6)−2(+3)=6
EmassofK2Cr2O7=6Mol.massofK2Cr2O7