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Question

Chemistry Question on d -and f -Block Elements

Equivalent mass of K2Cr2O7 {K_2Cr_2O_7} in acidic solution is equal to

A

molecular mass/2

B

molecular mass/4

C

molecular mass

D

molecular mass/6

Answer

molecular mass/6

Explanation

Solution

{\overset{\text{+6}}{ {C}}r_2 O^{2-}_7 + 14 H^+ + 6e^- -> 2Cr^{3+} + 7H_2O }
Total number of electrons gained = 6
Total change in oxidation number of Cr
???? =2(+6)2(+3)=62(+6) - 2(+3) = 6
EmassofK2Cr2O7=Mol.massofK2Cr2O76{Emass\, of \, K_2Cr_2O_7 = \frac{Mol.mass \, of \, K_2 Cr_2 O_7}{6} }