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Question

Chemistry Question on Thermodynamics

Enthalpy of sublimation of a substance is equal to

A

enthalpy of fusion + enthalpy of vapourisation

B

enthalpy of fusion

C

enthalpy of vapourisation

D

twice the enthalpy of vapourisation

Answer

enthalpy of fusion + enthalpy of vapourisation

Explanation

Solution

Solid >[Sublimation] {->[Sublimation]} Vapour This process occurs in two steps, Step 11 : Solid >[Fusion] {->[Fusion]} Liquid Step 22 : Liquid >[Vaporisation] {->[Vaporisation]} Vapour Thus, Enthalpy of sublimation = Enthalpy of fusion + Enthalpy of vaporisation.