Question
Chemistry Question on Thermodynamics
Enthalpy of sublimation of a substance is equal to
A
enthalpy of fusion + enthalpy of vapourisation
B
enthalpy of fusion
C
enthalpy of vapourisation
D
twice the enthalpy of vapourisation
Answer
enthalpy of fusion + enthalpy of vapourisation
Explanation
Solution
Solid −>[Sublimation] Vapour This process occurs in two steps, Step 1 : Solid −>[Fusion] Liquid Step 2 : Liquid −>[Vaporisation] Vapour Thus, Enthalpy of sublimation = Enthalpy of fusion + Enthalpy of vaporisation.