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Question: Enthalpy of neutralisation of four acids A, B, C and D with NaOH are -10.5, -13.7, -5.9 and -12.7 kc...

Enthalpy of neutralisation of four acids A, B, C and D with NaOH are -10.5, -13.7, -5.9 and -12.7 kcal eq1^{-1} respectively. Out of A, B, C and D strongest acid is

A

C

B

A

C

D

D

B

Answer

B

Explanation

Solution

The strongest acid gives the most exothermic neutralisation. Comparing the magnitudes:

  • Acid A: 10.5 kcal
  • Acid B: 13.7 kcal
  • Acid C: 5.9 kcal
  • Acid D: 12.7 kcal

Acid B has the highest magnitude (13.7 kcal), so it is the strongest acid.