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Question

Chemistry Question on Electrochemistry

Electrolysis of dilute aqueous NaClNaCl solution was carried out by passing 10mA10\, mA current. The time required to liberate 0.01mole0.01\, mole of H2H_2 gas at the cathode is (1F=96500Cmol1)(1 \,F\,= 96500 \,C \,mol^{-1})

A

9.65×104s9.65 \times 10^4 s

B

19.3×104s19.3 \times 10^4 s

C

28.95×104s28.95 \times 10^4 s

D

38.6×104s38.6 \times 10^4 s

Answer

19.3×104s19.3 \times 10^4 s

Explanation

Solution

0.01mol0.01\, mol of H2=0.02gH_2 = 0.02 g equivalent
\Rightarrow Coulombs required =0.02×96500=1930C= 0.02 \times 96500=1930\, C
\Rightarrow \hspace40mm Q=It= 1930\, C
\Rightarrow \hspace35mm t= \frac{1930}{10 \times 10^{-3}}=19.3 \times 10^4 s