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Question

Question: Electrolysis of a solution of MnSO4 in aqueous sulphuric acid is a method for the preparation of MnO...

Electrolysis of a solution of MnSO4 in aqueous sulphuric acid is a method for the preparation of MnO2. Passing a current of 27A for 24 hours gives 1kg of MnO2. The current efficiency in this process is :

A

100%

B

95.185%

C

80%

D

82.951%

Answer

95.185%

Explanation

Solution

1000×2(55+32)=27×24×3600×η96500orη=0.951=95.1%\frac{1000 \times 2}{(55 + 32)} = \frac{27 \times 24 \times 3600 \times \eta}{96500}or\eta = 0.951 = 95.1\%