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Question: Electrode potential data of few cells is given below. Based on the data, arrange the ions in increas...

Electrode potential data of few cells is given below. Based on the data, arrange the ions in increasing order of their reducing power.

Fe(aq)3++eFe(aq)2+;Eº=+0.77VFe_{(aq)}^{3 +} + e^{-} \rightarrow Fe_{(aq)}^{2 +};Eº = + 0.77V

Al(aq)3++3eAl(s);Eº=1.66VAl_{(aq)}^{3 +} + 3e^{-} \rightarrow Al_{(s)};Eº = - 1.66V

Br2(aq)+2e2Br(aq);Eº=+1.09VBr_{2(aq)} + 2e^{-} \rightarrow 2Br_{(aq)}^{-};Eº = + 1.09V

A

Br<Fe2+<AlBr^{-} < Fe^{2 +} < Al

B

Fe2+<Al<BrFe^{2 +} < Al < Br^{-}

C

Al<Br<Fe2+Al < Br^{-} < Fe^{2 +}

D

Al<Fe2+<BrAl < Fe^{2 +} < Br^{-}

Answer

Br<Fe2+<AlBr^{-} < Fe^{2 +} < Al

Explanation

Solution

Lower the reduction potential more is the reducing

power.

Br<Fe2+<AlBr^{-} < Fe^{2 +} < Al