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Question

Chemistry Question on Structure of atom

Ejection of the photoelectron from metal in the photoelectric effect experiment can be stopped by applying 0.5V0.5\, V when the radiation of 250nm250\, nm is used. The work function of the metal is :

A

4 eV

B

4.5 eV

C

5 eV

D

5.5 eV

Answer

4.5 eV

Explanation

Solution

From photoelectric experiment, we have

hv=hv0+(K.E.)maxh v=h v_{0}+( K.E. )_{\max }
hvλ=W+(K.E.)max\frac{h v}{\lambda}=W+( K . E .)_{\max }

where hvλ\frac{h v}{\lambda} is the energy of incident radiation, WW is the work function and (K.E.)max( K . E .)_{\max } is the kinetic energy of the ejected electrons.

hvλ=W+(K.E.)max\frac{h v}{\lambda} =W+( K.E. )_{\operatorname{max}}
6.6×1034×3×108256.7×109×1.6×1019\frac{6.6 \times 10^{-34} \times 3 \times 10^{8}}{256.7 \times 10^{9} \times 1.6 \times 10^{-19}} =W+0.5=W+0.5 (As 1V=1eV1\, V =1\, eV )

4.95eV=W+0.5eVW=4.45eV4.95\, eV =W+0.5\, eV \Rightarrow W=4.45\, eV