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Question

Chemistry Question on The solid state

Each of the following solids show, the Frenkel defect except

A

ZnS

B

AgBr

C

AgI

D

KCl

Answer

KCl

Explanation

Solution

In KCl, co-ordination number of cation and anion is 6 and 6 respectively. KCl is highly ionic so Schottky defect is common. Note : Schottky defect is common in compounds having high coordination nummber while Frenkel defect is common in compounds with low coordination number.