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Question: \({E^{0}}_{RP}\)or Fe+/Fe and Sn+2/Sn are - 0.44 and 0.14 volts respectively. The standard emf for c...

E0RP{E^{0}}_{RP}or Fe+/Fe and Sn+2/Sn are - 0.44 and 0.14 volts respectively. The standard emf for cell.

Fe+2+SnSn+2+FeFe^{+ 2} + Sn\overset{\quad\quad}{\rightarrow}Sn^{+ 2} + Feis

A
  • 0.30 V
B
  • 0.58 V
C
  • 0.58 V
D
  • 0.30 V
Answer
  • 0.58 V
Explanation

Solution

Fe+2+SnSn+2+FeFe^{+ 2} + Sn\overset{\quad\quad}{\rightarrow}Sn^{+ 2} + Fe

E0cell=E0Fe2+/Fe+E0Sn/Sn+2{E^{0}}_{cell} = {E^{0}}_{Fe2 + /Fe} + {E^{0}}_{Sn/Sn^{+ 2}}

= - 0.44 - 0.14 = - 0.58 V