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Question

Chemistry Question on Electrochemistry

During the electrolysis of molten sodium chloride, the time required to produce 0.100.10 mol of chlorine gas using a current of 33 amperes is

A

55 minutes

B

110 minutes

C

220 minutes

D

330 minutes

Answer

110 minutes

Explanation

Solution

At Cathode:
2H2O>[2e]H2+2OH{2H_2O ->[2e^{-}] H_2 + 2OH^{-}}
At anode:
2Cl>[2e]Cl2+2e{2Cl^{-} ->[2e^{-}] Cl_2 + 2e^{-}}
WE=It96500\frac{W}{E} = \frac{It}{96500}
0.1×2=3×t(sec)965000.1 \times 2 = \frac{3 \times t(sec)}{96500}
t = 6433 sec
t = 107.2 min
\sim 110 min.