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Chemistry Question on Chemical Kinetics

During nuclear explosion, one of the products is 90Sr^{90}Sr with half-life of 28.1 years. If 1µg of 90Sr^{90}Sr was absorbed in the bones of a newly born baby instead of calcium, how much of it will remain after 10 years and 60 years if it is not lost metabolically.

Answer

k=0.693t1/2=0.69328.1 Y1k = \frac {0.693}{t_{1/2}} = \frac {0.693}{28.1} \ Y^{-1}
Here,
It is known that,

t=2.303klog [R]0[R]t = \frac {2.303}{k} log \ \frac {[R]_0}{[R]}

10=2.3030.693/28.1log 1R10 = \frac {2.303}{0.693/28.1} log \ \frac {1}{R}

10=2.3030.693/28.1(log [R])10 = \frac {2.303}{0.693/28.1} (-log \ [R])

log [R]=10×0.6932.303×28.1log \ [R] =\frac { 10\times 0.693}{2.303\times28.1}

[R]=antilog (0.1071)[R] = antilog \ (-0.1071)

[R]=antilog(1ˉ.8929)[R] = antilog (\bar1.8929)

[R]=0.7814 µg[R] = 0.7814 \ µg

Therefore, 0.7814 µg of 90Sr^{90}Sr will remain after 10 years.

t=2.303klog [R]0[R]t = \frac {2.303} {k}log \ \frac {[R]_0}{[R]}

60=2.3030.693/28.1log 1R60 = \frac {2.303}{0.693/28.1} log \ \frac {1}{R}

60=2.3030.693/28.1(log [R])60 = \frac {2.303}{0.693/28.1} (-log \ [R])

log [R]=60×0.6932.303×28.1log \ [R] =\frac { 60\times 0.693}{2.303\times28.1}

[R]=antilog (0.6425)[R] = antilog \ (-0.6425)

[R]=antilog (1ˉ.3575)[R] = antilog \ (\bar1.3575)

[R]=0.2278 µg[R] = 0.2278\ µg

Therefore, 0.2278 µg of 90Sr^{90}Sr will remain after 60 years.