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Question: Double bond equivalent of cubane is: ![](https://www.vedantu.com/question-sets/3c37bae0-5ae1-4198-...

Double bond equivalent of cubane is:

A.44
B. 55
C. 66
D. 77

Explanation

Solution

Double bond equivalent is used to calculate the number of unsaturation present in an organic molecule. The term unsaturated means a double bond or a ring in a molecule structure. It is the total number of pi bonds present in the structure.
Formula used:
DBE=C+1H2+N2DBE=C+1-\dfrac{H}{2}+\dfrac{N}{2}
where, DBEDBE is the double bond equivalent, CC is the number of carbon atoms, HH is the number of hydrogen atoms, NN is the number of nitrogen atoms in the molecule.

Complete step by step answer:
An unsaturated molecule is a molecule that contains double bond and triple bond and can undergo additional reactions. For example, alkenes contain one double bond and have a general formula CnH2n{{C}_{n}}{{H}_{2n}}. Double bond equivalent is used to calculate the level of unsaturation in a molecule. The formula used for double bond equivalent is:
DBE=C+1H2+N2DBE=C+1-\dfrac{H}{2}+\dfrac{N}{2}
where, DBEDBE is the double bond equivalent, CC is the number of carbon atoms, HH is the number of hydrogen atoms, NN is the number of nitrogen atoms in the molecule.
The molecular formula of cubane is C8H8{{C}_{8}}{{H}_{8}}. Here, the number of carbon atoms is 88, the number of hydrogen atoms is 88 and the number of nitrogen atoms is 00.
On substituting the values in the above formula, we get,
DBE=8+182+02DBE=8+1-\dfrac{8}{2}+\dfrac{0}{2}
DBE=5\Rightarrow DBE=5
Therefore, the double bond equivalent of cubane is 55.

Hence, the correct option is (B).

Additional information:
Cubane is a solid crystalline substance that has a molecular formula C8H8{{C}_{8}}{{H}_{8}} and consists of eight carbon atoms that are arranged at the corners of a cube and one hydrogen atom is attached to each carbon atom. It is a synthetic hydrocarbon molecule.

Note: The structure of cubane contains six rings that correspond to the six faces of a cube.
-The molecular formula of cubane is C8H8{{C}_{8}}{{H}_{8}}.It is a solid crystalline substance and a member of prismanes.
-Double bond equivalent is used to determine the degree of unsaturation in a molecule.