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Question

Chemistry Question on Chemical bonding and molecular structure

dπpπd\pi - p \pi bond present in :

A

NO2NO_2^-

B

NO3NO_3^-

C

PO43PO_4^{3-}

D

CO32CO_3^{2-}

Answer

PO43PO_4^{3-}

Explanation

Solution

In P-O bond, π\pi-bond is formed by the sidewise overlapping of d-orbital of P and p-orbital of oxygen.
Hence, it is formed by pπp\pi and dπd \pi-overlapping.
In nitrogen and carbon, no vacant d-orbital is present. So, they do not form pπdπp\pi - d \pi bond.