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Question

Question: \(CsBr\) crystal has \(bcc\) structure. It has an edge length of \(4.3Å.\) The shortest interionic d...

CsBrCsBr crystal has bccbcc structure. It has an edge length of 4.3A˚.4.3Å. The shortest interionic distance between Cs+Cs^{+} and BrBr^{-}ions is.

A

1.86A˚1.86Å

B

3.72A˚3.72Å

C

4.3A˚4.3Å

D

7.44A˚7.44Å

Answer

3.72A˚3.72Å

Explanation

Solution

Closest approach in bcc lattice

=12= \frac{1}{2} of body diagonal =12×3a= \frac{1}{2} \times \sqrt{3}a =32×4.3=3.72A˚= \frac{\sqrt{3}}{2} \times 4.3 = 3.72Å.