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Question

Chemistry Question on d -and f -Block Elements

Cr2+Cr^{2+} is reducing and Mn3+Mn^{3+} is oxidising. Cr2+Cr^{2+} and Mn3+Mn^{3+} have d4d^4 configuration.

A

If both assertion and reason are true and reason is the correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion

C

If assertion is true but reason is false

D

If both assertion and reason are false

Answer

If both assertion and reason are true but reason is not the correct explanation of assertion

Explanation

Solution

Cr2+Cr^{2+} is reducing as its configuration changes from d4d^4 to d3d^3 (half-filled t2gt_{2g}). The change from Mn3+Mn^{3+} to Mn2+Mn^{2+} results in the half-filled d5d^5 configurations which has extra stability.