Question
Chemistry Question on Hydrocarbons
Correct order of stability is :
A
1-butene > Trans-2-butene > Cis-2-butene
B
Trans-2-butene > Cis-2-butene > 1-butene
C
Trans-2-butene > 1-butene > Cis-2-butene
D
Cis-2-butene > Trans-2-butene > 1-butene
Answer
Trans-2-butene > Cis-2-butene > 1-butene
Explanation
Solution
Stability of alkene \hspace20mm \propto\frac{1}{Heat\, of\, hydrogenation\, of\, alkene} Stability of an alkene depends upon the heat of hydrogenation of an alkene. Therefore, the lower the heat of hydrogenation of an alkene, higher will be stability.
Order of stability is
trans-2-butene > cis-2-butene > 1-butene.
Heat of hydrogenation (kJ/mol) are 115.5,119.6 and 126.8 respectively.