Question
Chemistry Question on coordination compounds
Correct increasing order for the wavelengths of absorption in the visible region the complexes of Co3+ is :
A
[Co(H2O)6]3+,[Co(en)3]3+,[Co(NH3)6]3+
B
[Co(H2O)6]3+,[Co(NH3)6]3+,[Co(en)3]3+
C
[Co(NH3)6]3+,[Co(en)3]3+,[Co(H2O)6]3+
D
[Co(en)3]3+,[Co(NH3)6]3+,[Co(H2O)6]3+
Answer
[Co(en)3]3+,[Co(NH3)6]3+,[Co(H2O)6]3+
Explanation
Solution
The order of the ligand in the spectrochemical series
H2O<NH3<en
Hence, the wavelength of the light observed will be in the order
[Co(en)3]3+,[Co(NH3)6]3+,[Co(H2O)6]3+