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Question

Chemistry Question on d block elements

Copper sulphate solution reacts with KCNKCN to give

A

Cu(CN)2Cu(CN)_2

B

CuCNCuCN

C

K2[Cu(CN)4]K_2 [Cu(CN)_4]

D

K3[Cu(CN)4]K_3[Cu(CN)_4]

Answer

K3[Cu(CN)4]K_3[Cu(CN)_4]

Explanation

Solution

\ceCuSO4+2KCN>Cu(CN)2+K2SO4\ce{CuSO4 + 2KCN->Cu (CN)2 + K2SO4}
\ce2Cu(CN)2>Cu2(CN)2or2CuCN+\ce{2Cu (CN)2->Cu2 (CN)2 \,or\, 2CuCN +}
\ceCNCNcyanogen\underset{\text{cyanogen}}{\ce{CN - CN}}
\ceCuCN+3KCN>K3\ce{CuCN+ 3KCN->K3} \ce[Cu(CN)4]colourless\underset{\text{colourless}}{\ce{[Cu(CN)4]}}