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Question

Chemistry Question on Chemical bonding and molecular structure

Considering xx-axis as the internuclear axis, which out of the following will not form a sigma bond.

A

1s and 1s

B

1s and 2px2{{p}_{x}}

C

2py2{{p}_{y}} and 2py2{{p}_{y}}

D

1s and 2s

Answer

2py2{{p}_{y}} and 2py2{{p}_{y}}

Explanation

Solution

2py2{{p}_{y}} and 2py2{{p}_{y}} will not form a σ\sigma - bond because on taking x-axis as internuclear axis 2py2{{p}_{y}} and 2py2{{p}_{y}} orbitals overlap sideway (lateral overlapping) resulting in the formation of a π\pi - bond.