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Question: Consider the ground state of \( Cr\left( {Z = 24} \right) \) .The no. of electrons with the azimutha...

Consider the ground state of Cr(Z=24)Cr\left( {Z = 24} \right) .The no. of electrons with the azimuthal quantum no. l=1l = 1 and 22 respectively are-
(A)16&4\left( A \right)16\& 4
(B)12&5\left( B \right)12\& 5
(C)12&4\left( C \right)12\& 4
(D)16&5\left( D \right)16\& 5

Explanation

Solution

The ground state of any element is the lowest energy level. When atoms absorb energy they move on to higher levels and these are known as excited states. The quantum numbers of electrons define the exact location of electrons. The azimuthal quantum number gives us the information of the number of subshells the electron is present.

Complete answer:
The atomic number of Chromium is 24, the electron configuration of Chromium is 1s22s22p63s23p64s13d51{s^2}2{s^2}2{p^6}3{s^2}3{p^6}4{s^1}3{d^5}
The azimuthal quantum number ll has values as

Value of llThe subshell it represents
0s
1p
2d

The electrons in the ground state of Chromium with azimuthal quantum l=1l = 1 and 22 correspond to subshells p and d respectively.
From, the electron configuration of Cr the number of electrons in l=1l = 1 which corresponds to the subshells p will be equal to the sum of electrons in 2p62{p^6} and 3p63{p^6} subshells which is equal to 6+6=126 + 6 = 12
And from the electron configuration of Cr the number of electrons in l=2l = 2 which corresponds to the subshells d will be equal to the number of electrons in 3d53{d^5} which is equal to 5.
Therefore, the number of electrons in the azimuthal quantum number l=1l = 1 and 22 are 12 and 5 respectively.
Option \left( B \right)12\ & 5 , is the correct choice among the options.

Note:
The principal quantum number (n) represents the shell (K, L, M, N) in which the electron is present. And the value of azimuthal quantum number ll depends on n , l=n1l = n - 1 . Which means that the first shell can have one subshell, the second shell can have two subshells.

Shell number (n)The no subshellAzimuthal quantum no.Shape of subshell
110s
220,1s, p
330,1,2s, p, d