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Question: Consider the ground state of \( Cr \) atom \( \left( Z\text{ }=\text{ }24 \right). \) The numbers of...

Consider the ground state of CrCr atom (Z = 24).\left( Z\text{ }=\text{ }24 \right). The numbers of electrons with the azimuthal quantum numbers, l = 1l\text{ }=\text{ }1 and 22 are, respectively:

Explanation

Solution

We know that quantum number is a set of numbers with the help of which we can locate the position of an electron in an atom. There are four quantum numbers in total and using them we can calculate the number of electrons in a shell and subshell of an element.

Complete answer:
We all know that there are four quantum numbers including: Principal quantum number tells us about the size of the electron cloud and energy level of the electron and is represented by n.n. The shells K, L, M, N, O, PK,\text{ }L,\text{ }M,\text{ }N,\text{ }O,\text{ }P have the n=1,2,3,4,5,6 n=1,2,3,4,5,6~ respectively. The azimuthal quantum number tells us about the shape of electron could and subshell to which the electron belongs, represented as ll and subshells s, p, d, f, gs,\text{ }p,\text{ }d,\text{ }f,\text{ }g have l=0,1,2,3,4 l=0,1,2,3,4~ respectively.
The magnetic quantum number tells us about the orientation of the electron cloud, represented by mm and for a given value of l, ml,\text{ }m can be ll to 00 to +l+l and finally the spin quantum number which tells about the spin or rotation of the electron in its own axis. The electronic configuration of CrCr along with the values of the quantum numbers nn and ll are shown.

| nn | 11
---|---|---
1s21{{s}^{2}} | 11 | 00
2s22{{s}^{2}} | 22 | 00
2p62{{p}^{6}} | 22 | 11
3s23{{s}^{2}} | 33 | 00
3p63{{p}^{6}} | 33 | 11
3d53{{d}^{5}} | 33 | 22
4s14{{s}^{1}} | 44 | 00

Thus the number of electrons with l=1l=1 is 1212 and the number of electrons with l=2l=2 is 5.5.
Therefore, the correct answer is 1212 and 55 respectively.

Note:
Remember that the probability of finding an electron is said to be zero in case of radial nodes. Angular nodes are equal to the value of azimuthal quantum number, and since the value for azimuthal quantum number for d orbital is two, the value for angular nodes also has to be two. The number of nodes increases when the principal quantum number increases.