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Question

Chemistry Question on Reaction Mechanisms & Synthesis

Consider the given chemical reaction :
reaction 1
Product ''A'' is :

A

picric acid

B

oxalic acid

C

acetic acid

D

adipic acid

Answer

adipic acid

Explanation

Solution

The reaction of cyclohexane with potassium permanganate (KMnO4\text{KMnO}_4) in an acidic medium (H2SO4\text{H}_2\text{SO}_4) and heat results in the oxidation of cyclohexane to adipic acid.
Step 1: Oxidation of cyclohexane
Cyclohexane (C6H12\text{C}_6\text{H}_{12}) undergoes oxidation in the presence of KMnO4\text{KMnO}_4 and H2SO4\text{H}_2\text{SO}_4.
- The KMnO4\text{KMnO}_4 oxidizes the CH2-\text{CH}_2- groups in cyclohexane to carboxylic acid (COOH-\text{COOH}) groups.
- This results in the formation of adipic acid (HOOC(CH2)4COOH\text{HOOC} - (\text{CH}_2)_4 - \text{COOH}).
C6H12[KMnO4,H2SO4,Heat]HOOC(CH2)4COOH(Adipic Acid)\text{C}_6\text{H}_{12} \rightarrow [\text{KMnO}_4, \text{H}_2\text{SO}_4, \text{Heat}] \text{HOOC} - (\text{CH}_2)_4 - \text{COOH} \, (\text{Adipic Acid})
Step 2: Conclusion
The product AA is adipic acid.
Final Answer: (4).